Summary of Outlook Autodiscover Order
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Issue: You would like a better understanding of the order in which Outlook goes through the Autodiscover process
SCP lookup: Outlook will query Active Directory for Autodiscover information. If that fails, Outlook begins it's "non-domain connected" logic, and will go in order down this list
HTTPS root domain query: Outlook, if not domain joined, queries using the primary email address domain (right hand side of the email address). Using this domain as an example, it will search for https://enterpriseit.co/autodiscover/autodiscover.xml
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